Of course, you'll have to fiddle with the levels to make it look right, but it's pretty much an out of the box and up-and-running experience for something with a computer inside it.
The important thing then becomes how many HDMI holes it has in the back vs. the number of cables you want feeding the thing.
Which in your case is one, but I'd demand two just in case you ever decide you'd like cable TV or whatever.
The trouble with Smart TVs is that they can be pretty poorly maintained when it comes to software updates; a year or two in and they're basically abandonware. The only thing I use mine for (app-wise) is Netflix, because all my servers and things are Linux-based and can't do DRM. And the Netflix app is terrible.
If my home setup were Apple centric (and I didn't develop this sort of thing for fun and profit), the Apple TV would be all I'd get.
The reason I recommend it is because you'll be able to access all your content from your various computers -- certainly anything that can be put in iTunes, and that includes movies you rip yourself with third party software like handbrake or source in other ways we won't go into -- and anything that it doesn't provide an app for you can fling at it from one of those devices. And it does have the characteristic Apple virtue that what it does have is less broken than everybody else.
Depending on whether the app's media type and location is supported by Chromecast, the 'source' device may actually be doing the work of fetching and rendering the material and 'casting' the A/V output to Chromecast, but commonly it's just sending the URL and various tokens and chromecast is doing the actual fetching/decoding.
It's similar to having an Airplay-only device on your TV; bearing in mind that they are similar protocols but not the same nor interchangeable. Its main disadvantage is that it can't play content that's local to your network, so if you have your own movies and things you have to play them on your device and screencast it to chromecast. Which may or may not be well supported and look decent. For several good reasons I'd rather tell the TV-attached gizmo "play this file, which you can find over on that computer", than tie up some other device playing it and throwing the video to the TV. You can do the latter with Apple TV as well, but the thing is you don't have to, at least for any content that's supported by iTunes.
I ended up buying a matched soundbar from the same vendor (Panasonic Viera), one that uses HDMI and connects to the ARC-enabled port on the TV, which means basically all three gizmos (HTPC+CEC running XBMC, TV and soundbar) can be controlled with just the TV remote. It also means if I turn off the TV and just use the HTPC/XBMC + soundbar for music, the xbmc mobile app can control the speaker volume.
It's all basically as straightforward and usable as it can get. If I were going to buy a Smart TV again I might get a Samsung or Vizio, as there's a Plex app available for both. Which is a whole nother topic. (I don't use Plex myself but it's what I'd recommend to pretty much anyone I didn't recommend Apple TV to, i.e. someone who doesn't have a houseful of predominantly Apple goodies already.)
I avoided the price-attractive Vizio after reading a large number of reviews of later models that suffer from persistent random reboot issues. No point in a smart TV that can't be a TV reliably IMO. The picture on my Father-in-Law's Samsung (dumb) TV is outstanding.
I went Sony only because I have a good experience with Sony products, their tech support was rated higher than everyone else's and they offer four HDMI inputs to everyone else's two. It seemed to me that I'd be bunging wires into it from all over the place and better to find I had too many sockets than too few. I'm also familiar with the Sony video family "quirks" and it seemed likely I would have a better time getting the clown out of the picture.
I think it's better to go with the direct-connected HTPC because transcode-network-decode-display is a lot more bother than just decode-display; but not having a HTPC would be attractive if your Smart TV was actually smart enough to do everything you want, and playing local media in whatever format is a major sticking point.
Yesterday he was being interviewed on NPR as I was driving home and the interviewer asked about the difference between what people, upon recognizing him, were likely to shout to him in America as opposed to the UK.
His answer was interesting but too long to go into here. It did, however, include a snippet that might allow for much japing should one of us encounter the great man in the future.
He said that often, people would make reference to sketches that he couldn't remember participating in, and he would just smile and nod and say something neutrally agreeable to fake it.
So the next time you see John Cleese, get close, make yourself known (this may involve acting as I know none of you would never slip into nudge-nudge, wink-wink territory normally, being too cool for that nonsense, but the payoff for doing so will, er, pay off) and say something like: "What about that time you were the astronaut lost among the vikings, who all turned out to be women? Talk about funny! I only saw it on DVD, and they blanked the punchline. What was it you said right at the end there, when "Mrs" Eric the Viking Idle showed you "her" buttocks and demanded an autograph?"