The temporal lobe controls your ability to concentrate, and is more active when a brain is concentrating on something. A typical pattern in an ADD brain is that when it is used to concentrate deliberately on something then the temporal lobe is actually deactivated (ie there is less neural activity). I say "deliberately" because a common ADD behaviour is 'hyperfocus' where the brain will concentrate on something novel1 to the exclusion of all else, but this is rarely deliberate.
Note that there is another book called "Healing ADD" by Thom Hartmann, that I would also recommend, but which is entirely different. In particular, Mr Hartmann specifically attacks Amens' work in scanning brains. But there we are.
[1] another very annoying aspect of this is that I cannot go to sleep if there is speech in earshot. I'll be drifting off quite satisfactorily when my brain will latch on to the interesting noises and amplify them in my perception. Similarly, I need silence or at least white noise if I need to think about a task which I am not entirely involved in, because otherwise my mind will concentrate on the novel rather than what I'm supposed to be doing.